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Abstract: The precise fabrication of multifunctional materials is essential for advancing next-generation energy, sensing, and space systems technologies. This talk will present recent developments in Direct Write Assembly (DWA) techniques, enabling the bottom-up construction of architected materials with tailored properties. Emphasis will be given to integrating functional inks, additive manufacturing strategies, and post-processing treatments that enhance performance across diverse applications. Case studies will illustrate how DWA can address challenges in solar energy harvesting, chemical sensing, and structural components for extraterrestrial environments.